Search Results

Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO3 (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn4+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/?-Al2O3 (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO2).

Downsizing and downspeeding are two efficient strategies to reduce vehicles CO2 emission, provided that high BMEP can be achieved at any engine speed under clean, safe, stable and efficient combustion. With a 6:1 minimum compression ratio, the MCE-5 VCRi achieves 40 bar peak BMEP at 1200 rpm with no irregular combustion. If peak BMEP is maintained below 35 bar, fuel enrichment is no longer necessary. When running at part loads, the engine operates at high compression ratios (up to 15:1) to minimize BSFC and maximize the sweet spot area on the map. Next generation MCE-5 VCRi engines will combine VCR and stoichiometric charges, highly diluted with external cooled EGR, in order to improve part loads efficiency by means of both the reduction in heat and pumping losses, and the optimization of compression-expansion ratio. This strategy, added to downsizing-donwspeeding, requires high-energy ignition systems to promote repeatable, stable, rapid and complete combustion.

A conceptual project aimed at understanding the fundamental design considerations concerning the implementation of catalyst systems on outboard marine engines was carried out by Mercury Marine, with the support of the California Air Resources Board. In order to keep a reasonable project scope, only electronic fuel injected four-stroke outboards were considered. While they represent a significant portion of the total number of outboard engines sold in the United States, carbureted four-strokes and direct injected two-strokes pose their own sets of design constraints and were considered to be outside the scope of this study. Recently, three-way catalyst based exhaust emissions aftertreatment systems have been introduced into series production on sterndrive and inboard marine spark ignition engines in North America. The integration of catalyst systems on outboards is much more challenging than on these other marine propulsion alternatives.

This paper reports results of an experimental investigation performed on a commercial diesel engine supplied with fuel blends having low cetane number to attain a simultaneous reduction in NOx and smoke emissions. Blends of 20% and 40% of n-butanol in conventional diesel fuel have been tested, comparing engine performance and emissions to diesel ones. Taking advantage of the fuel blend higher resistance to auto ignition, it was possible to extend the range in which a premixed combustion is achieved. This allowed to match the goal of a significant reduction in emissions without important penalties in fuel consumption. The experimental activity was carried on a turbocharged, water cooled, 4 cylinder common rail DI diesel engine. The engine equipment included an exhaust gas recirculation system controlled by an external driver, a piezo-quartz pressure transducer to detect the in-cylinder pressure signal and a current probe to acquire the energizing current to the injector.

Combustion engines are typically only 20-30% efficient at part-load operating conditions, resulting in poor fuel economy on average. To address this, LiquidPiston has developed an improved thermodynamics cycle, called the High-Efficiency Hybrid Cycle (HEHC), which optimizes each process (stroke) of the engine operation, with the aim of maximizing fuel efficiency. The cycle consists of: 1) a high compression ratio; 2) constant-volume combustion, and 3) over-expansion. At a modest compression ratio of 18:1, this cycle offers an ideal thermodynamic efficiency of 74%. To embody the HEHC cycle, LiquidPiston has developed two very different rotary engine architectures ? called the ?M? and ?X? engines. These rotary engine architectures offer flexibility in executing the thermodynamics cycle, and also result in a very compact package. In this talk, I will present recent results in the development of the LiquidPiston engines. The company is currently testing 20 and 40 HP versions of the ?M?

Nitrous Oxide (N2O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 [1,2] (298-310 times more potent than carbon dioxide (CO2)). As a result, any aftertreatment system that generates N2O must be well understood to be used effectively. Under low temperature conditions, N2O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N2O formed by the thermal decomposition of ammonium nitrate [3]. Ammonium nitrate and N2O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO2)[4]. This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO2 ratio above 1. However, N2O has also been observed at relatively high temperatures, in the region of 500°C.

Four-way, integrated, diesel emission control systems that combine selective catalytic reduction for NOx control with a continuously regenerating trap to remove diesel particulate matter were evaluated under real-world, on-road conditions. Tests were conducted using a semi-tractor with an emissions year 2000, 6-cylinder, 12 L, Volvo engine rated at 287 kW at 1800 rpm and 1964 N-m. The emission control system was certified for retrofit application on-highway trucks, model years 1994 through 2002, with 4-stroke, 186-373 kW (250-500 hp) heavy-duty diesel engines without exhaust gas recirculation. The evaluations were unique because the mobile laboratory platform enabled evaluation under real-world exhaust plume dilution conditions as opposed to laboratory dilution conditions. Real-time plume measurements for NOx, particle number concentration and size distribution were made and emission control performance was evaluated on-road.

Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.

In this project funded by the Bayerische Forschungsstiftung two fundamental investigations had been carried out: first a new N-rich liquid ammonia precursor solution based on guanidine salts had been completely characterized and secondly a new type of side-flow reactor for the controlled catalytic decomposition of aqueous NH3 precursor to ammonia gas has been designed, applied and tested in a 3 liter passenger car diesel engine. Guanidine salts came into the focus due to the fact of a high nitrogen-content derivate of urea (figure 1). Specially guanidinium formate has shown extraordinary solubility in water (more than 6 kg per 1 liter water at room temperature) and therefore a possible high ammonia potential per liter solution compared to the classical 32.5% aqueous urea solution (AUS32) standardized in ISO 22241 and known as DEF (diesel emission fluid), ARLA32 or AdBlue®. Additionally a guanidine based formulation could be realized with high freezing stability down to almost ?30 °C (?

The 48 papers in this technical paper collection focus on exhaust emission control. Topics covered include the durability of particulate filters and exhaust catalysts, analysis of aged catalysts and filters, PF technologies, testing protocols, SCR technology, thermal stress resistance, and more. The 48 papers in this technical paper collection focus on exhaust emission control. Topics covered include the durability of particulate filters and exhaust catalysts, analysis of aged catalysts and filters, PF technologies, testing protocols, SCR technology, thermal stress resistance, and more. The 48 papers in this technical paper collection focus on exhaust emission control. Topics covered include the durability of particulate filters and exhaust catalysts, analysis of aged catalysts and filters, PF technologies, testing protocols, SCR technology, thermal stress resistance, and more.

The 16 papers in this technical paper collection cover diesel engine exhaust aftertreatment system models as well as the validation and application. Technologies covered include DOC, HC trap, DFP, LNT, SCR, ammonia oxidation catalysts, hybrid or combined catalysts, urea-water solution spray dynamics, and mixture non-uniformity.

The 16 papers in this technical paper collection covers particle emissions from combustion engines including measurement and testing methods, effects of changes in fuel composition, environmental and health effects of elemental carbon and organic carbon that constitutes solid cored particles plus the environmental and health effects of secondary organic aerosol emissions.

This technical paper collection covers topics such as: new materials for lean NOx traps (LNT) and Selective Catalytic Reduction (SCR); system integration and durability; advances in NOx catalyst substrates, novel reductants and mixing designs.

This technical paper collection focuses on the general topic of combustion engine gaseous emissions (regulated and non-regulated). This includes well-to-wheels CO2 production for alternative technologies, fuel economy and all greenhouse gas emission research. It also includes hydrocarbon species and specific NOx species production over aftertreatment devices as a result of changes in fuel specification and the inclusion of bio-derived components and consideration of secondary emissions production (slip) as a result of aftertreatment.

The 55 papers in this technical paper collection cover new developments; particulate filter systems; system integration and durability; particle filter substrates, and selective catalytic reduction (SCR) process of exhaust emissions.

Topics included in this technical paper collection are the integration of various diesel particulate matter (PM) and diesel Nitrogen Oxide (NOx) reduction technologies plus analogous technologies for the growing population of direct injection gasoline engines.

This technical paper collection will focus on ‘Advances in NOx Reduction Technology’. The topics covered will include: new materials for lean NOx traps (LNT) and Selective Catalytic Reduction (SCR); system integration and durability; advances in NOx catalyst substrates, novel reductants and mixing designs.

The papers included in this collection cover engine combustion control and optimization techniques. Topics include engine combustion diagnostics as specialized for control, control methodologies and algorithms, optimization, related combustion sensing, etc.

Design Optimization Methods and Application collecion features papers on new and improved optimization techniques and on application of different optimization methods in component and vehicle design. Methods include deterministic and stochastic optimization techniques. Applications range from noise pressure optimization and vehicle dynamic response optimization to sub-system topology and shape and full vehicle gage and topology optimization.

Separate sub-sessions cover powertrain control, calibration, and system-level optimization processes related to achieving stringent market fuel economy, emissions, performance, reliability, and quality demands. Topics include the control, calibration, and diagnostics of the engine, powertrain, and subsystems related to energy management in conventional and hybrid operation, considering the simultaneous optimization of hardware design parameters and control software calibration parameters.